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Ba3Yb(BO3)3 single crystals. Growth and spectroscopic characterization

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dc.creator Solé Vicente, Ricard, 1962-
dc.creator Güell Vilà, Frank
dc.creator Gavaldà, Josefina
dc.creator Aguiló Díaz, Magdalena
dc.creator Díaz, Francesc (Díaz González)
dc.date 2011-05-25T10:54:01Z
dc.date 2011-05-25T10:54:01Z
dc.date 2008
dc.date.accessioned 2024-12-16T10:27:07Z
dc.date.available 2024-12-16T10:27:07Z
dc.identifier 0884-2914
dc.identifier http://hdl.handle.net/2445/18199
dc.identifier 561651
dc.identifier.uri http://fima-docencia.ub.edu:8080/xmlui/handle/123456789/21913
dc.description We obtained Ba3Yb(BO3)3 single crystals by the flux method with solutions of the BaB2O4Na2OYb2O3 system. The evolution of the cell parameters with temperature shows a slope change at temperatures near 873 K, which may indicate a phase transition that is not observed by changes appearing in the x-ray powder patterns or by differential thermal analysis (DTA). The evolution of the diffraction patterns with the temperature shows incongruent melting at temperatures higher than 1473 K. DTA indicates that there is incongruent melting and this process is irreversible. Ba3Yb(BO3)3 has a wide transparency window from 247 to 3900 nm. We recorded optical absorption and emission spectra at room and low temperature, and we determined the splitting of Yb3+ ions. We used the reciprocity method to calculate the maximum emission cross section of 0.28 10-20 cm2 at 966 nm. The calculated lifetime of Yb3+ in Ba3Yb(BO3)3 is trad = 2.62 ms, while the measured lifetime is t = 3.80 ms.
dc.format 7 p.
dc.format application/pdf
dc.language eng
dc.publisher Materials Research Society
dc.relation Reproducció del document publicat a: http://dx.doi.org/10.1557/JMR.2008.0313
dc.relation Journal of Materials Research, 2008, vol. 23, núm. 9, p. 2512-2518
dc.relation http://dx.doi.org/10.1557/JMR.2008.0313
dc.rights (c) Materials Research Society, 2008
dc.rights info:eu-repo/semantics/openAccess
dc.source Articles publicats en revistes (Enginyeria Electrònica i Biomèdica)
dc.subject Creixement cristal·lí
dc.subject Cristal·lografia
dc.subject Crystal growth
dc.subject Crystallography
dc.title Ba3Yb(BO3)3 single crystals. Growth and spectroscopic characterization
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/publishedVersion


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