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Effect of doping on lead-free dielectric ceramics

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dc.contributor Mestres i Vila, Ma. Lourdes
dc.creator Fàbregas Bellavista, Paula
dc.date 2018-02-07T13:40:34Z
dc.date 2018-02-07T13:40:34Z
dc.date 2018-01
dc.date.accessioned 2024-12-16T10:26:09Z
dc.date.available 2024-12-16T10:26:09Z
dc.identifier http://hdl.handle.net/2445/119657
dc.identifier.uri http://fima-docencia.ub.edu:8080/xmlui/handle/123456789/20593
dc.description Treballs Finals de Grau de Química, Facultat de Química, Universitat de Barcelona, Any: 2018, Tutora: Lourdes Mestres
dc.description Piezoelectric materials are widely used nowadays in a large number of electronic devices considering their exceptional electrical properties. Lead zirconate titanate (PZT) is the most currently used piezoelectric material; it presents a perovskite structure and has a region, called morphotropic phase boundary (MPB), where an improvement of its properties occurs. However, the major inconvenience with this material is the environmental and health problems arising from the presence of lead as a result of its high toxicity. For this reason the need for researching on lead-free ceramics with similar properties that PZT shows has been recently one of the main objectives of the scientific community. Bi0.5Na0.5TiO3–BaTiO3 (BNT-BT) system is a promising choice for being the substitute of PZT due to the fact that it has perovskite structure as well as a MPB where great piezoelectric response is obtained. Notwithstanding, even with the large number of studies carried out the exact composition where its properties are as remarkable as the PZT ones has not been found. Consequently, it is necessary to continue investigating in this direction. This work is based on the study of how the addition of zirconium as a doping element affects BNT-BT properties. The preparation of BNT-BT based ceramics has been made by solid state reaction with variations on the synthesis conditions and composition of the ceramics. Their characterization has been accomplished with the different techniques used on solid state chemistry. Through XRD the introduction of dopants on the BNT-BT structure has been confirmed and by SEM/EDS ceramics could be found where in the structure the dopant goes. Furthermore, the dielectric likewise the ferroelectric properties could have been studied, obtaining different results depending on the synthesis conditions carried through and the composition
dc.format 49 p.
dc.format application/pdf
dc.language eng
dc.rights cc-by-nc-nd (c) Fàbregas, 2018
dc.rights http://creativecommons.org/licenses/by-nc-nd/3.0/es/
dc.rights info:eu-repo/semantics/openAccess
dc.source Treballs Finals de Grau (TFG) - Química
dc.subject Piezoelectricitat
dc.subject Plom
dc.subject Química de l'estat sòlid
dc.subject Ceràmiques electròniques
dc.subject Treballs de fi de grau
dc.subject Piezoelectricity
dc.subject Lead
dc.subject Solid state chemistry
dc.subject Electronic ceramics
dc.subject Bachelor's theses
dc.title Effect of doping on lead-free dielectric ceramics
dc.title Efecte del dopatge en ceràmiques dielèctriques lliures de plom
dc.type info:eu-repo/semantics/bachelorThesis


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